دانلود intermediate organic chemistry کتاب شیمی آلی Fabirkiewicz ویرایش 3

دانلود intermediate organic chemistry کتاب شیمی آلی Fabirkiewicz ویرایش 3

کتاب شیمی آلی برای دانشجویان شیمی به ویژه کارشناسی ارشد ویرایش 3 سوم Intermediate Organic Chemistry, 3rd Edition نوشته و تالیف Ann M. Fabirkiewicz, John C. Stowell یکی از بهترین کتاب های تخصصی مرجع در زمینه شیمی آلی که مفاهیم و سرفصل های شیمی آلی به خصوص در مقطع کارشناسی ارشد را به زبان ساده و گویا همراه با مکانیسم های ان ها به خوبی شرح و توضیح داده است.

مشخصات کتاب

• عنوان انگلیسی:  intermediate organic chemistry
• عنوان فارسی : شیمی آلی برای دانشجویان ارشد
• فرمت فایل: PDF
• حجم فایل فشرده:  8.88 مگابایت 
• ویرایش: 3
• سال انتشار: 2015
• زبان نوشتاری: انگلیسی
• نویسنده(ها):  Ann M. Fabirkiewicz, John C. Stowell
• تعداد صفحات: 374 صفحه
• تعداد فصل ها: 10 فصل
• نحوه دریافت : دریافت فوری و آنی لینک دانلود فایل بعد از پرداخت

فهرست مطالب و عناوین فصل های کتاب

1 Reading Nomenclature 1
1.1 Acyclic Polyfunctional Molecules, 2
1.2 Monocyclic Aliphatic Compounds, 3
1.3 Bridged Polycyclic Structures, 4
1.4 Fused Polycyclic Compounds, 6
1.5 Spiro Compounds, 10
1.6 Monocyclic Heterocyclic Compounds, 12
1.7 Fused‐Ring Heterocyclic Compounds, 14
1.8 Bridged and Spiro Heterocyclic Compounds, 19
Resources, 20
Problems, 21
References,22
2 Accessing Chemical Information 25
2.1 Databases, 25
2.2 Chemical Literature, 26
2.3 Synthetic Procedures, 29
2.4 Health and Safety Information, 30
Problems, 32
References, 33
3 S tereochemistry 35
3.1 Representations, 35
3.2 Vocabulary, 37
3.3 Property Differences Among Stereoisomers, 40
3.4 Resolution of Enantiomers, 44
3.5 E nantioselective Synthesis, 47
3.6 Reactions at a Stereogenic Atom, 49
3.6.1 Racemization, 49
3.6.2 Epimerization, 50
3.6.3 Inversion, 51
3.6.4 Retention, 51
3.6.5 Transfer, 52
3.7 Relative and Absolute Configuration, 53
3.8 Topism, 56
Resources, 59
Problems, 60
References, 65
4 Mechanisms and Predictions 69
4.1 Reaction Coordinate Diagrams and Mechanisms, 69
4.2 T he Hammond Postulate, 71
4.3 Methods for Determining Mechanisms, 72
4.3.1 Identification of Products and Intermediates, 72
4.3.2 Isotope Tracing, 73
4.3.3 Stereochemical Determination, 74
4.3.4 Concentration Dependence of Kinetics, 75
4.3.5 Isotope Effects in Kinetics, 85
4.3.6 T emperature Effects on Kinetics, 87
4.3.7 Substituent Effects on Kinetics, 90
4.4 Representative Mechanisms, 95
4.4.1 Reactions in Basic Solution, 96
4.4.2 Reactions in Acidic Solution, 100
4.4.3 Free‐Radical Reactions, 103
4.4.4 Molecular Rearrangements, 106
Resources, 108
Problems, 109
References, 120
5 E lectron Delocalization, Aromatic Character,
and Pericyclic Reactions 123
5.1 Molecular Orbitals, 124
5.2 Aromatic Character, 130
5.3 Pericyclic Reactions, 135
5.3.1 Cycloaddition Reactions, 137
5.3.2 E lectrocyclic Reactions, 142
5.3.3 Sigmatropic Reactions, 147
Resources, 152
Problems, 152
References, 158
6 Functional Group Transformations 163
6.1 Carboxylic Acids and Related Derivatives, 164
6.1.1 Carboxylic Acids, 164
6.1.2 Carboxylic Esters, 166
6.1.3 Carboxylic Amides, 168
6.1.4 Carboxylic Acid Halides, 168
6.1.5 Carboxylic Anhydrides, 169
6.1.6 Nitriles, 169
6.1.7 O rtho Esters, 170
6.2 Aldehydes, Ketones, and Derivatives, 171
6.2.1 Aldehydes, 171
6.2.2 Ketones, 174
6.2.3 Imines and Enamines, 175
6.2.4 Acetals, 175
6.2.5 Vinyl Ethers, 177
6.3 Alcohols, 179
6.4 Ethers, 179
6.5 Alkyl Halides, 181
6.5.1 Alkyl Chlorides and Alkyl Bromides, 182
6.5.2 Alkyl Iodides, 184
6.5.3 Alkyl Fluorides, 184
6.6 Amines, 185
6.7 Isocyanates, 187
6.8 Alkenes, 187
6.9 Reductive Removal of Functionality, 190
Resources, 191
Problems, 191
References, 198
7 Carbon–Carbon Bond Formation 205
7.1 Carbon–Carbon Single Bond Formation, 206
7.1.1 Reactions in Basic Solution, 206
7.1.2 Reactions in Acidic Solution, 214
7.1.3 O rganometallic Coupling Reactions, 217
7.2 Carbon–Carbon Double‐Bond Formation, 218
7.3 Multibond Processes, 222
Resources, 224
Problems, 224
References, 230
8 Planning Multistep Syntheses 235
8.1 Retrosynthetic Analysis, 235
8.2 Disconnection at a Functional Group
or Branch Point, 236
8.3 Cooperation for Difunctionality, 244
8.4 Ring Closure, 250
8.5 Acetylide Alkylation and Addition, 253
8.6 T he Diels–Alder Reaction, 255
8.7 T he Claisen Rearrangement, 259
8.8 Synthetic Strategies, 263
8.9 Final Note, 265
Resources, 266
Problems, 266
References, 271
9 Physical Influences on Reactions 277
9.1 Unimolecular Reactions, 278
9.2 Homogenous Two‐Component Reactions, 279
9.3 T emperature Effects, 280
9.4 Pressure Effects, 281
9.5 Solvent Effects, 282
9.6 Biphasic Reactions, 283
9.6.1 Phase Transfer Catalysis, 283
9.6.2 Increasing Solubility, 286
9.6.3 Increasing Surface Area, 287
9.6.4 Ultrasound, 287
9.7 Reactions on Chemical Supports, 288
9.8 Using Unfavorable Equilibria, 291
9.9 Green Chemistry, 293
Resources, 294
Problems, 294
References, 295
10 Survey of Organic Spectroscopy 299
10.1 E lectromagnetic Radiation, 299
10.2 Ultraviolet Spectroscopy, 300
10.2.1 O rigin of the Signals, 300
10.2.2 Interpretation, 302
10.2.3 Visible Spectroscopy, 302
10.3 Infrared Spectroscopy, 303
10.3.1 O rigin of the Signals, 304
10.3.2 Interpretation, 304
10.4 Mass Spectrometry, 305
10.4.1 O rigin of the Signals, 306
10.4.2 Interpretation, 307
10.5 N MR Spectroscopy, 309
10.5.1 O rigin of the Signals, 309
10.5.2 Interpretation of Proton NMR Spectra, 311
10.6 Carbon NMR Spectra, 323
10.6.1 General Characteristics, 323
10.6.2 Interpretation of 13C NMR Spectra, 325
10.7 Correlation of 1H and 13C NMR Spectra, 327
Resources, 329
Problems, 329
References, 333
Appendix A 337
Appendix B 341
Index 347