دانلود کتاب مبانی شیمی آلی اوتلت Robert Ouellette ویرایش 1 + حل المسائل

دانلود کتاب مبانی شیمی آلی اوتلت Robert Ouellette ویرایش 1 + حل المسائل

کتاب مبانی شیمی آلی اوتلت ویرایش 1 اول Principles of Organic Chemistry 1st Edition نوشته و تالیف Robert Ouellette J. David Rawn رابرت اوتلت یکی از کتاب های مرجع و تخصصی مفید و ارزشمند در زمینه آموزش مفاهیم و اصول شیمی آلی برای دانشجویان و اساتید شیمی آلی می باشد. این کتاب از انتشارات elsevier در سال 2015 به چاپ رسیده است.

مشخصات کتاب

• عنوان انگلیسی:  Principles of Organic Chemistry
• عنوان فارسی : مبانی و اصول شیمی آلی
• فرمت فایل: PDF
• حجم فایل فشرده:  7.55 مگابایت 
• ویرایش: 1
• سال انتشار: 2015
• شابک: 9780128024447, 0128024445
• زبان نوشتاری: انگلیسی
• نویسنده(ها):  Robert Ouellette J. David Rawn
• تعداد صفحات: 497 صفحه
• تعداد فصل ها: 16 فصل

فهرست مطالب و عناوین فصل های کتاب

CHAPTER 1 STRUCTURE OF ORGANIC COMPOUNDS 1
1.1 ORGANIC AND INORGANIC COMPOUNDS 1
1.2 ATOMIC STRUCTURE 1
1.3 TYPES OF BONDS 4
1.4 FORMAL CHARGE 7
1.5 RESONANCE STRUCTURES 8
1.6 PREDICTING THE SHAPES OF SIMPLE MOLECULES 10
1.7 ORBITALS AND MOLECULAR SHAPES 11
1.8 FUNCTIONAL GROUPS 15
1.9 STRUCTURAL FORMULAS 18
1.10 ISOMERS 23
1.11 NOMENCLATURE 25
EXERCISES 27
CHAPTER 2 PROPERTIES OF ORGANIC COMPOUNDS 33
2.1 STRUCTURE AND PHYSICAL PROPERTIES 33
2.2 CHEMICAL REACTIONS 38
2.3 ACID-BASE REACTIONS 39
2.4 OXIDATION-REDUCTION REACTIONS 41
2.5 CLASSIFICATION OF ORGANIC REACTIONS 44
2.6 CHEMICAL EQUILIBRIUM AND EQUILIBRIUM CONSTANTS 45
2.7 EQUILIBRIA IN ACID-BASE REACTIONS 47
2.8 EFFECT OF STRUCTURE ON ACIDITY 49
2.9 INTRODUCTION TO REACTION MECHANISMS 51
2.10 REACTION RATES 54
EXERCISES 58
CHAPTER 3 ALKANES AND CYCLOALKANES 65
3.1 CLASSES OF HYDROCARBONS 65
3.2 ALKANES 65
3.3 NOMENCLATURE OF ALKANES 68
3.4 CONFORMATIONS OF ALKANES 72
3.5 CYCLOALKANES 75
3.6 CONFORMATIONS OF CYCLOALKANES 78
3.7 PHYSICAL PROPERTIES OF ALKANES 81
3.8 OXIDATION OF ALKANES AND CYCLOALKANES 83
3.9 HALOGENATION OF SATURATED ALKANES 84
CHAPTER 4 ALKENES AND ALKYNES 95
4.1 UNSATURATED HYDROCARBONS 95
4.2 GEOMETRIC ISOMERISM 99
4.3 E,Z NOMENCLATURE OF GEOMETRICAL ISOMERS 101
4.4 NOMENCLATURE OF ALKENES AND ALKYNES 103
4.5 ACIDITY OF ALKENES AND ALKYNES 106
4.6 HYDROGENATION OF ALKENES AND ALKYNES 107
4.7 OXIDATION OF ALKENES AND ALKYNES 110
4.8 ADDITION REACTIONS OF ALKENES AND ALKYNES 111
4.9 MECHANISM OF ADDITION REACTIONS 113
4.10 HYDRATION OF ALKENES AND ALKYNES 115
4.11 PREPARATION OF ALKENES AND ALKYNES 116
4.12 ALKADIENES (DIENES) 119
4.13 TERPENES 120
SUMMARY OF REACTIONS 124
EXERCISES 126
CHAPTER 5 AROMATIC COMPOUNDS 133
5.1 AROMATIC COMPOUNDS 133
5.2 AROMATICITY 134
5.3 NOMENCLATURE OF AROMATIC COMPOUNDS 137
5.4 ELECTROPHILIC AROMATIC SUBSTITUTION 139
5.5 STRUCTURAL EFFECTS IN ELECTROPHILIC AROMATIC SUBSTITUTION 143
5.6 INTERPRETATION OF RATE EFFECTS 145
5.7 INTERPRETATION OF DIRECTING EFFECTS 148
5.8 REACTIONS OF SIDE CHAINS 150
5.9 FUNCTIONAL GROUP MODIFICATION 152
5.10 SYNTHESIS OF SUBSTITUTED AROMATIC COMPOUNDS 154
SUMMARY OF REACTIONS 156
EXERCISES 158
CHAPTER 6 STEREOCHEMISTRY 163
6.1 CONFIGURATION OF MOLECULES 163
6.2 MIRROR IMAGES AND CHIRALITY 163
6.3 OPTICAL ACTIVITY 167
6.4 FISCHER PROJECTION FORMULAS 168
6.5 ABSOLUTE CONFIGURATION 170
6.6 MOLECULES WITH MULTIPLE STEREOGENIC CENTERS 173
6.7 SYNTHESIS OF STEREOISOMERS 178
6.8 REACTIONS THAT PRODUCE STEREOGENIC CENTERS 179
6.9 REACTIONS THAT FORM DIASTEREOMERS 182
EXERCISES 184
CHAPTER 7 NUCLEOPHILIC SUBSTITUTION
AND ELIMINATION REACTIONS 189
7.1 REACTION MECHANISMS AND HALOALKANES 189
7.2 NUCLEOPHILIC SUBSTITUTION REACTIONS 192
7.3 NUCLEOPHILICITY VERSUS BASICITY 194
7.4 MECHANISMS OF SUBSTITUTION REACTIONS 197
7.5 SN2 VERSUS SN1 REACTIONS 200
7.6 MECHANISMS OF ELIMINATION REACTIONS 201
7.7 EFFECT OF STRUCTURE ON COMPETING REACTIONS 203
SUMMARY OF REACTIONS 206
EXERCISES 206
CHAPTER 8 ALCOHOLS AND PHENOLS 209
8.1 THE HYDROXYL GROUP 209
8.2 PHYSICAL PROPERTIES OF ALCOHOLS 212
8.3 ACID-BASE REACTIONS OF ALCOHOLS 214
8.4 SUBSTITUTION REACTIONS OF ALCOHOLS 215
8.5 DEHYDRATION OF ALCOHOLS 216
8.6 OXIDATION OF ALCOHOLS 218
8.7 SYNTHESIS OF ALCOHOLS 221
8.8 PHENOLS 226
8.9 SULFUR COMPOUNDS: THIOLS AND THIOETHERS 229
SUMMARY OF REACTIONS 231
EXERCISES 232
CHAPTER 9 ETHERS AND EPOXIDES 239
9.1 STRUCTURE OF ETHERS 239
9.2 NOMENCLATURE OF ETHERS 240
9.3 PHYSICAL PROPERTIES OF ETHERS 241
9.4 THE GRIGNARD REAGENT AND ETHERS 242
9.5 SYNTHESIS OF ETHERS 244
9.6 REACTIONS OF ETHERS 245
9.7 SYNTHESIS OF EPOXIDES 246
9.8 REACTIONS OF EPOXIDES 246
SUMMARY OF REACTIONS 254
EXERCISES 255
CHAPTER 10 ALDEHYDES AND KETONES 259
10.1 THE CARBONYL GROUP 259
10.2 NOMENCLATURE OF ALDEHYDES AND KETONES 261
10.3 PHYSICAL PROPERTIES OF ALDEHYDES AND KETONES 263
10.4 OXIDATION-REDUCTION REACTIONS OF CARBONYL COMPOUNDS 265
10.5 ADDITION REACTIONS OF CARBONYL COMPOUNDS 267
10.6 SYNTHESIS OF ALCOHOLS FROM CARBONYL COMPOUNDS 269
10.7 ADDITION REACTIONS OF OXYGEN COMPOUNDS 272
10.8 FORMATION OF ACETALS AND KETALS 274
10.9 ADDITION OF NITROGEN COMPOUNDS 275
10.10 REACTIVITY OF THE a-CARBON ATOM 278
10.11 THE ALDOL CONDENSATION 279
SUMMARY OF REACTIONS 282
EXERCISES 284
CHAPTER 11 CARBOXYLIC ACIDS AND ESTERS 287
11.1 CARBOXYLIC ACIDS AND ACYL GROUPS 287
11.2 NOMENCLATURE OF CARBOXYLIC ACIDS 289
11.3 PHYSICAL PROPERTIES OF CARBOXYLIC ACIDS 292
11.4 ACIDITY OF CARBOXYLIC ACIDS 294
11.5 SYNTHESIS OF CARBOXYLIC ACIDS 297
11.6 NUCLEOPHILIC ACYL SUBSTITUTION 300
11.7 REDUCTION OF ACYL DERIVATIVES 304
11.8 ESTERS AND ANHYDRIDES OF PHOSPHORIC ACID 305
11.9 THE CLAISEN CONDENSATION 308
SUMMARY OF REACTIONS 309
EXERCISES 311
CHAPTER 12 AMINES AND AMIDES 315
12.1 ORGANIC NITROGEN COMPOUNDS 315
12.2 BONDING AND STRUCTURE OF AMINES 316
12.3 STRUCTURE AND CLASSIFICATION OF AMINES AND AMIDES 317
12.4 NOMENCLATURE OF AMINES AND AMIDES 319
12.5 PHYSICAL PROPERTIES OF AMINES 322
12.6 BASICITY OF NITROGEN COMPOUNDS 325
12.7 SOLUBILITY OF AMMONIUM SALTS 328
12.8 NUCLEOPHILIC REACTIONS OF AMINES 328
12.9 SYNTHESIS OF AMINES 331
12.10 HYDROLYSIS OF AMIDES 333
12.11 SYNTHESIS OF AMIDES 334
SUMMARY OF REACTIONS 334
EXERCISES 336
CHAPTER 13 CARBOHYDRATES 343
13.1 CLASSIFICATION OF CARBOHYDRATES 343
13.2 CHIRALITY OF CARBOHYDRATES 344
13.3 HEMIACETALS AND HEMIKETALS 349
13.4 CONFORMATIONS OF MONOSACCHARIDES 353
13.5 REDUCTION OF MONOSACCHARIDES 354
13.6 OXIDATION OF MONOSACCHARIDES 354
13.7 GLYCOSIDES 356
13.8 DISACCHARIDES 358
13.9 POLYSACCHARIDES 362
SUMMARY OF REACTIONS 365
EXERCISES 366
CHAPTER 14 AMINO ACIDS, PEPTIDES, AND PROTEINS 371
14.1 PROTEINS AND POLYPEPTIDES 371
14.2 AMINO ACIDS 371
14.3 ACID-BASE PROPERTIES OF α-AMINO ACIDS 372
14.4 ISOIONIC POINT 376
14.5 PEPTIDES 377
14.6 PEPTIDE SYNTHESIS 380
14.7 DETERMINATION OF PROTEIN STRUCTURE 382
14.8 PROTEIN STRUCTURE 386
EXERCISES 393
CHAPTER 15 SYNTHETIC POLYMERS 397
15.1 NATURAL AND SYNTHETIC MACROMOLECULES 397
15.2 STRUCTURE AND PROPERTIES OF POLYMERS 397
15.3 CLASSIFICATION OF POLYMERS 399
15.4 METHODS OF POLYMERIZATION 40115.5 ADDITION POLYMERIZATION 404
15.6 COPOLYMERIZATION OF ALKENES 405
15.7 CROSS-LINKED POLYMERS 406
15.8 STEREOCHEMISTRY OF ADDITION POLYMERIZATION 408
15.9 CONDENSATION POLYMERS 410
15.10 POLYESTERS 411
15.11 POLYCARBONATES 413
15.12 POLYAMIDES 414
15.13 POLYURETHANES 415
EXERCISES 416
CHAPTER 16 SPECTROSCOPY 421
16.1 SPECTROSCOPIC STRUCTURE DETERMINATION 421
16.2 SPECTROSCOPIC PRINCIPLES 422
16.3 ULTRAVIOLET SPECTROSCOPY 424
16.4 INFRARED SPECTROSCOPY 425
16.5 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY 431
16.6 SPIN-SPIN SPLITTING 435
16.7 13C NMR SPECTROSCOPY 439
EXERCISES 442
Solutions to In-Chapter Problems 447
Index 477