Coordination Chemistry: The Chemistry of Metal Complexes
- نویسنده(ها): Fred Basolo, Ronald C. Johnson
- ویرایش: 2
- سال انتشار: 1964
- تعداد صفحات: 148 صفحه
- تعداد فصل ها: 7 فصل
- فرمت فایل: PDF
- حجم فایل فشرده: 2.86 مگابایت
99,000 تومان
Coordination Chemistry: The Chemistry of Metal Complexes
کتاب شیمی کئوردیناسیون: شیمی کمپلکس های فلزی ویرایش 2 دوم Coordination Chemistry: The Chemistry of Metal Complexes از کتاب های مرجع تخصصی شیمی معدنی در زمینه بررسی شیمی کوئورديناسيون و ترکیبات کئوردیناسیون معدنی و انواع کمپلکس های فلزی که توسط دو نفز از اساتید شیمی معدنی Fred Basolo, Ronald C. Johnson نوشته و تالیف شده است.
مشخصات کتاب:
Coordination Chemistry: The Chemistry of Metal Complexes
فهرست مطالب و عناوین فصل های کتاب
1. Introduction and Historical Development 1
1.1 Introduction 1
1.2 Historical development 2
1.3 Nomenclature 9
Problems 15
2. The Coordinate Bond 17
2.1 The electron-pair bond 17
2.2 Electronic structure of the atom 19
2.3 The concept of effective atomic number 23
2.4 Valence bond theory 25
2.5 Crystal field theory 26
2.6 Molecular orbital theory 37
Problems 43
3. Stereochemistry 45
3.1 Geometry of coordination compounds 45
3.2 Complexes with unusual structural features 49
3.3 Isomerism in metal complexes 52
Problems 61
4. Preparations and Reactions of Coordination Compounds 63
4.1 Substitution reactions in aqueous solution 64
4.2 Substitution reactions in nonaqueous solvents 65
4.3 Substitution reactions in the absence of solvents 66
4.4 Thermal dissociation of solid complexes
4.5 Photochemical synthesis 68
4.6 Oxidation–reduction reactions 69
4.7 Catalysis 70
4.8 Substitution reactions without metal–ligand bond cleavage 72
4.9 Trans effect 74
4.10 Synthesis of cis–trans isomers 75
4.11 Preparation of optically-active compounds 77
Problems 78
5. Complex Ion Stability 80
5.1 Stability constants 82
5.2 Factors that influence complex stability 83
5.3 Stabilization of unusual oxidation states by coordination 92
5.4 Determination of stability constants 93
Problems 95
6. Kinetics and Mechanisms of Reactions of Coordination Compounds 97
6.1 Rate of a reaction 98
6.2 The rate law 99
6.3 Effective collisions 101
6.4 Inert and labile complexes 103
6.5 Mechanisms of substitution reactions 106
6.6 Octahedral substitution reactions 107
6.7 Square planar substitution 111
6.8 Mechanisms for redox reactions 114
Problems 118
7. Organometallic Chemistry and Current Research Topics 120
7.1 Preparation of metal carbonyls and organometallic compounds 120
7.2 Organometallic reactions and homogeneous catalysis 128
7.3 Metals in living systems 131
7.4 Solid state chemistry
Problems
دیدگاهها
هیچ دیدگاهی برای این محصول نوشته نشده است.